Y Sakamoto et al 1996 J. Phys.: Condens. Matter 8 3399 doi:10.1088/0953-8984/8/19/015
Y Sakamoto, K Takai, I Takashima and M Imada
Show affiliationsThe simultaneous measurement of both the relative electrical resistance and the equilibrium hydrogen and deuterium pressure as a function of composition of Pd - H and Pd - D systems have been carried out at temperatures between 273 and 323 K at
pressures up to about 3.3 MPa. The relative resistance,
, in the
two-phase region for the absorption processes shows a very small and almost linear increase with increasing H(D) content, especially for the Pd - H system, compared to the larger changes previously observed by the electrolysis method. The resistance behaviour is quite similar to the shape of p - c isotherm relationships. The relative resistance increments per unit change of H(D)/Pd content at 298 K,
, in the
two-phase region are about 1.5 and 2.1 times larger for the Pd - H and Pd - D systems, respectively, compared to the changes in the relative lattice parameters with H(D)/Pd content,
, within the two-phase region, where
is the lattice parameter of H(D)-free Pd and r is the atom ratio. On the other hand, the resistance increment in the
single solid solution phase and
single phase, except for the higher-H(D)-content region, is significantly larger compared to the changes of the lattice expansion due to dissolved hydrogen and deuterium. Thus, the variation in resistance with hydrogen and deuterium content in the
two-phase region may be mainly associated with an incoherent formation of
hydride within the
phase. The relative resistance for the subsequent desorption processes from the absorption up to about 3.3 MPa at 298 K in both Pd - H and Pd - D systems exhibits almost the same maximum as that of the absorption processes, i.e.
at about
and
at about
, and then the
values decrease gradually with decreasing H(D) content up to the
phase boundary composition; on entering the
two-phase region, the
values remain almost constant, i.e.
for the Pd - H system and
for the Pd - D system. This large hysteresis of resistance can be attributed to the creation of `lattice strain deformations' accompanied by dislocation formation from
hydride (deuteride) formation and by further highly dissolved hydrogen and deuterium in the
phase region.
72.80.-r Conductivity of specific materials
62.20.F- Deformation and plasticity
82.80.-d Chemical analysis and related physical methods of analysis
61.72.Cc Kinetics of defect formation and annealing
Condensed matter: electrical, magnetic and optical
Surfaces, interfaces and thin films
Issue 19 (6 May 1996)
Received 11 December 1995
Y Sakamoto et al 1996 J. Phys.: Condens. Matter 8 3399
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