Stability and magnetic properties of an iron-mercury alloy

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Published under licence by IOP Publishing Ltd
, , Citation S Linderoth and S Morup 1992 J. Phys.: Condens. Matter 4 8627 DOI 10.1088/0953-8984/4/44/024

0953-8984/4/44/8627

Abstract

Iron amalgams have been studied by Mossbauer spectroscopy and magnetization measurements between 7 and 425 K. The Mossbauer spectra at 12 K show that the iron is present in at least two different sites. After heat treatments the Mossbauer spectra change into the typical spectrum of alpha -Fe, and the magnetic moment per iron atom, at 275 K increases. It is suggested that the iron forms a metastable alloy with mercury, which decomposes at about 360 K. The Fe-Hg alloy is found to be ferromagnetically ordered with a corresponding Curie temperature of about 445 K.

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10.1088/0953-8984/4/44/024