M A Carpenter et al 2010 J. Phys.: Condens. Matter 22 035406 doi:10.1088/0953-8984/22/3/035406
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transition in LaAlO3: IV. An incipient instability below room temperature
M A Carpenter1, A Buckley1, P A Taylor1, R E A McKnight1 and T W Darling2,3
Show affiliationsResonant ultrasound spectroscopy has been used to characterize elastic softening and acoustic dissipation behaviour in single crystal and ceramic samples of LaAlO3 between 10 and 300 K. For the twinned
single crystals, average values of the cubic elastic moduli
and C44 were followed while the ceramic sample provided data for the bulk and shear moduli. A Debye-like dissipation peak occurs in the vicinity of 250 K, from which an activation energy of 43 ± 6 kJ mol−1 has been obtained. The mechanism for this is not known, but it is associated with C44 and therefore could be related in some way to the
transition at ~817 K. Slight softening in the temperature interval
K of resonance peaks determined by shear elastic moduli hints at an incipient Eg ferroelastic instability in LaAlO3. The softening interval ends with a further dissipation peak at ~60 K, the origin of which is discussed in terms of freezing of atomic motions of La and/or Al away from their high symmetry positions in the
structure. LaAlO3 thus shows evidence of incipient structural instability at low temperatures which is potentially analogous with the phenomenologically rich behaviour of SrTiO3.
81.40.Jj Elasticity and anelasticity, stress-strain relations
62.20.F- Deformation and plasticity
Issue 3 (27 January 2010)
Received 2 August 2009, in final form 13 November 2009
Published 21 December 2009
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transition in LaAlO3: IV. An incipient instability below room temperature
M A Carpenter et al 2010 J. Phys.: Condens. Matter 22 035406
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