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Elastic relaxations associated with the Pm\bar {3} m R\bar {3} c transition in LaAlO3: IV. An incipient instability below room temperature

M A Carpenter1, A Buckley1, P A Taylor1, R E A McKnight1 and T W Darling2,3

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Resonant ultrasound spectroscopy has been used to characterize elastic softening and acoustic dissipation behaviour in single crystal and ceramic samples of LaAlO3 between 10 and 300 K. For the twinned R\bar {3} c single crystals, average values of the cubic elastic moduli \case {1}{2}(C_{11}-C_{12}) and C44 were followed while the ceramic sample provided data for the bulk and shear moduli. A Debye-like dissipation peak occurs in the vicinity of 250 K, from which an activation energy of 43 ± 6 kJ mol−1 has been obtained. The mechanism for this is not known, but it is associated with C44 and therefore could be related in some way to the \mathrm {cubic \leftrightarrow
rhombohedral} transition at ~817 K. Slight softening in the temperature interval {\sim } 220 \to 70  K of resonance peaks determined by shear elastic moduli hints at an incipient Eg ferroelastic instability in LaAlO3. The softening interval ends with a further dissipation peak at ~60 K, the origin of which is discussed in terms of freezing of atomic motions of La and/or Al away from their high symmetry positions in the R\bar {3} c structure. LaAlO3 thus shows evidence of incipient structural instability at low temperatures which is potentially analogous with the phenomenologically rich behaviour of SrTiO3.


PACS

81.40.Jj Elasticity and anelasticity, stress-strain relations

62.20.F- Deformation and plasticity

64.70.K- Solid–solid transitions

81.30.Hd Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder

62.20.D- Elasticity

Subjects

Condensed matter: structural, mechanical & thermal

Dates

Issue 3 (27 January 2010)

Received 2 August 2009, in final form 13 November 2009

Published 21 December 2009



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