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Elastic relaxations associated with the Pm\bar 3 m R\bar 3c transition in LaAlO3: I. Single crystal elastic moduli at room temperature

M A Carpenter1, S V Sinogeikin2, J D Bass2, D L Lakshtanov2,4 and S D Jacobsen3

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Values for all six independent components of the \bar 3 m elastic modulus tensor of LaAlO3 perovskite are reported. These were determined by means of Brillouin scattering measurements of acoustic velocities in single crystal plates cut parallel to (110) and (100), as defined with respect to the cubic parent structure, and by pure-mode longitudinal and transverse sound velocity measurements along [100], [110] and [111] directions using GHz pulse-echo ultrasonics. The crystals contained intimate intergrowths of twins arising from the Pm\bar 3 m \leftrightarrow R\bar 3
c transition at higher temperature but, in combination with a careful analysis of twin orientation relationships, the two sets of data have allowed a unique solution to be obtained for individual twin components. The new data set represents an important contribution to the characterization of LaAlO3 single crystals which are widely used as the substrate for a plethora of different thin films with technological applications.


PACS

62.20.D- Elasticity

81.30.Hd Constant-composition solid-solid phase transformations: polymorphic, massive, and order-disorder

81.40.Jj Elasticity and anelasticity, stress-strain relations

78.35.+c Brillouin and Rayleigh scattering; other light scattering

62.65.+k Acoustical properties of solids

64.70.K- Solid–solid transitions

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 3 (27 January 2010)

Received 1 August 2009, in final form 14 October 2009

Published 21 December 2009



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