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Field dependence of temperature induced irreversible transformations of magnetic phases in Pr0.5Ca0.5Mn0.975Al0.025O3 crystalline oxide

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Archana Lakhani, Pallavi Kushwaha, R Rawat, Kranti Kumar, A Banerjee and P Chaddah

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FAST TRACK COMMUNICATION

Glass-like arrest has recently been reported in various magnetic materials. As in structural glasses, the kinetics of a first order transformation is arrested while retaining the higher entropy phase as a non-ergodic state. We show visual mesoscopic evidence of the irreversible transformation of the arrested antiferromagnetic–insulating phase in Pr0.5Ca0.5Mn0.975Al0.025O3 to its equilibrium ferromagnetic–metallic phase with an isothermal increase of magnetic field, similar to its iso-field transformation on warming. The magnetic field dependence of the non-equilibrium to equilibrium transformation temperature is shown to be governed by Le Chatelier's principle.


PACS

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

75.50.Lk Spin glasses and other random magnets

65.60.+a Thermal properties of amorphous solids and glasses: heat capacity, thermal expansion, etc.

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 3 (27 January 2010)

Received 25 September 2009, in final form 16 November 2009

Published 16 December 2009



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