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Unusual phase behavior of one-component systems with two-scale isotropic interactions

S V Buldyrev1, G Malescio2, C A Angell3, N Giovambattista4, S Prestipino2, F Saija5, H E Stanley6 and L Xu7

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We study the phase behavior of systems of particles interacting through pair potentials with a hard core plus a soft repulsive component. We consider several different forms of soft repulsion, including a square shoulder, a linear ramp and a quasi-exponential tail. The common feature of these potentials is the presence of two repulsive length scales, which may be the origin of unusual phase behaviors such as polyamorphism both in the equilibrium liquid phase and in the glassy state, water-like anomalies in the liquid state and anomalous melting at very high pressures.


PACS

64.70.D- Solid–liquid transitions

61.20.Gy Theory and models of liquid structure

64.70.P- Glass transitions of specific systems

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Dates

Issue 50 (16 December 2009)

Received 14 June 2009

Published 23 November 2009



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