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Evidence for a spin pseudogap in the normal state of superconducting Mo3Sb7

V H Tran1, A D Hillier2, D T Adroja2, Z Bukowski3 and W Miiller1

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Using muon spin relaxation (μSR) and inelastic neutron scattering (INS) we have investigated the normal state of the superconductor Mo3Sb7 and the reference compound Ru3Sn7. The μSR experiments on Ru3Sn7 reveal static and relatively slow dynamic relaxations, which are ascribed to a random static nuclear dipole field and thermally activated muon motion, respectively. INS experiments on Ru3Sn7, on the other hand, reveal three phononic excitations at 11, 18 and 23 meV, substantiating the assertion of Einstein and Debye oscillations derived from the specific heat and electrical resistivity data. The distinct difference in the μSR as well as INS spectra between Ru3Sn7 and Mo3Sb7 provides strong evidence for a magnetic/electronic nature of the phase transition at T* = 50 K in the Mo-based compound. On the basis of the μSR and INS data, the energy spin pseudogap of 150(10) K was estimated. The observed weak magnetism in the dynamic susceptibility χ''(Q,ω) and residual longitudinal field relaxation at 5 K imply a static ordering or quantum fluctuations.


PACS

74.25.Jb Electronic structure

74.70.Ad Metals; alloys and binary compounds (including A15, MgB2, etc.)

76.75.+i Muon spin rotation and relaxation

74.25.Kc Phonons

74.25.Fy Transport properties (electric and thermal conductivity, thermoelectric effects, etc.)

74.25.Bt Thermodynamic properties

Subjects

Superconductivity

Condensed matter: electrical, magnetic and optical

Dates

Issue 48 (2 December 2009)

Received 26 April 2009, in final form 6 October 2009

Published 30 October 2009



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