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An ab initio study of electronic and structural properties of Mn in a GaAs environment

A Z AlZahrani1, G P Srivastava1, R Garg2 and M A Migliorato2

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Based on ab initio calculations, we have investigated the atomic geometry, electronic properties and magnetic properties of Mn incorporation in GaAs. The inclusion of the Hubbard potential U in the calculation (namely with the σGGA+U scheme) results in the optimized geometry being contracted by approximately 2% relative to the relaxed geometry obtained by the (σGGA) method. Within both the σGGA and σGGA+U schemes the Mn impurity in bulk GaAs behaves like a d-hole with the majority spin state lying at 0.25 eV above the Fermi level. Theoretically simulated STM images for Mn/GaAs(110) indicate round protrusions at As sites and Ga sites, the latter being dependent on the Mn adsorption site (i.e. in different atomic layers). These results are supportive of a previous experimental STM image obtained with a very low Mn concentration.


PACS

71.20.Nr Semiconductor compounds

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

75.30.Cr Saturation moments and magnetic susceptibilities

73.20.Hb Impurity and defect levels; energy states of adsorbed species

75.50.Pp Magnetic semiconductors

61.66.Fn Inorganic compounds

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 48 (2 December 2009)

Received 22 September 2009, in final form 19 October 2009

Published 11 November 2009



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