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Devitrification of the glassy state in suspensions of charged platelets

M C D Mourad, A A Verhoeff, D V Byelov, A V Petukhov and H N W Lekkerkerker

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Colloidal suspensions of charged gibbsite platelets at salt concentrations of 10−2 M and below and with a sufficiently high particle concentration form a kinetically arrested, glassy state. We study the evolution of the glassy state in suspensions of three different gibbsite systems. Despite differences in size and polydispersity, we observe small, iridescent grains of the hexagonal columnar phase, for all these systems after periods of months to years. The connections between this devitrification phenomenon and the structure of the glassy state are discussed.


PACS

82.70.Dd Colloids

61.43.Fs Glasses

64.70.P- Glass transitions of specific systems

82.70.Kj Emulsions and suspensions

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 47 (25 November 2009)

Received 17 April 2009, in final form 8 July 2009

Published 5 November 2009



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