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Pattern formation during diffusional transformations in the presence of triple junctions and elastic effects

E A Brener1, G Boussinot1, C Hüter1, M Fleck1, D Pilipenko1, R Spatschek2 and D E Temkin1

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We compare different scenarios for dendritic melting of alloys with respect to the front propagation velocity. In contrast to conventional dendritic growth, selection can here be also due to the presence of a grain boundary or coherence strains, and the propagation speed is higher. The most favorable situation is partial melting, where two parabolic fronts, one melting and one solidifying interface, are moving together, since the process is then determined by diffusion in the thin liquid layer. There, and also in phase field simulations of melting in peritectic and eutectic systems, we observe a rotation of the triple junction relative to the growth direction. Finally, we discuss the role of elastic effects due to density and structural differences on solid-state phase transformations, and we find that they significantly alter the selection principles. In particular, we obtain free dendritic growth even with isotropic surface tension. This is investigated by Green's function methods and a phase field approach for growth in a channel and illustrated for the formation of a twin phase.


PACS

68.70.+w Whiskers and dendrites (growth, structure, and nonelectronic properties)

68.15.+e Liquid thin films

66.10.C- Diffusion and thermal diffusion

64.70.D- Solid–liquid transitions

68.03.Cd Surface tension and related phenomena

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 46 (18 November 2009)

Received 27 April 2009, in final form 20 July 2009

Published 27 October 2009



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