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Crossover from incommensurate to commensurate magnetic orderings in CoCr2O4

L J Chang1, D J Huang2, W-H Li3, S-W Cheong4, W Ratcliff5 and J W Lynn5

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The conical spin order of multiferroic CoCr2O4 has been studied by a neutron diffraction to investigate its magnetic phase transitions at temperatures below 40 K. Magnetic order of a spiral spin component with an incommensurate propagation vector of (0.63, 0.63, 0) was observed at 26 K, while at 14.5 K, the incommensurate conical spin order showed a transition into the fixed commensurate propagation vector of (2/3,2/3,0). In addition, two satellite peaks with propagation vectors of (0.035, 0, 0) and (0, 0.035, 0) from the commensurate vector were observed. The widths of these peaks indicate a long-range magnetic order. This new magnetic configuration below 14.5 K may lead to a new model of multiferroic behavior differing from the well-known spin–current model for magnetic ferroelectricity.


PACS

75.30.Wx Spin crossover

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

75.80.+q Magnetomechanical and magnetoelectric effects, magnetostriction

75.25.+z Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source x-ray scattering, etc.)

77.80.-e Ferroelectricity and antiferroelectricity

75.50.Dd Nonmetallic ferromagnetic materials

Subjects

Condensed matter: electrical, magnetic and optical

Dates

Issue 45 (11 November 2009)

Received 24 August 2009, in final form 7 October 2009

Published 23 October 2009



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