Quick search Find article
Quick search
Find article

Intricate coupling between ion–ion and ion–surface correlations in double layers as illustrated by charge inversion—combined effects of strong Coulomb correlations and excluded volume

Roland Kjellander

Show affiliations


Many-body correlations in electrolyte systems are important when the electrostatic coupling and/or the volume fraction of ions are not low. Such correlations are ignored in the traditional theories of electrolytes based on the Poisson–Boltzmann approximation. In the general case, the ion density profiles (ion–surface correlation functions) and the ion–ion correlation functions in diffuse electric double layers are strongly interdependent. Both have to be included in the treatment of the system to capture many essential properties. In this work the coupling between the ion–ion and ion–surface correlations and effects of this coupling are illustrated explicitly and graphically (visually). The average forces that act on the ions in the double layer are analysed. This leads to an understanding of mechanisms in action in the inhomogeneous electrolyte near a surface. Charge separation in an electrolyte outside an uncharged surface and charge inversion of highly charged surfaces are thereby used as examples of what insights can be gained by this kind of approach. Some links to mechanisms behind like-charge attraction are also discussed.


PACS

82.45.Gj Electrolytes

82.45.Jn Surface structure, reactivity and catalysis

Subjects

Surfaces, interfaces and thin films

Chemical physics and physical chemistry

Dates

Issue 42 (21 October 2009)

Received 28 March 2009

Published 29 September 2009



Related review articles

What's this?
View review articles related to this research to gain an insight into the key trends in this subject area. Related review articles are selected based on PACS/MSC codes, and are no more than three years old.

  1. Island growth in electrodeposition
  2. Theory of electrostatics and electrokinetics of soft particles
  3. Major applications of electrochemical techniques at national metrology institutes

View by subject




Export








Please login to access our web services, or create an account if you don't yet have one.

You must have cookies enabled in your web browser to be able to login.

Username
Password

Forgotten your password? Get a new one here.