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Helium cluster dissolution in molybdenum

O Runevall and N Sandberg

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Helium retention and diffusion in molybdenum is studied on an atomistic scale with ab initio methods. The thermal stability of helium–vacancy clusters is quantified within the framework of density functional theory. Calculated helium emission rates are used to derive a desorption spectrum which is compared with experimental results. The agreement between the current calculations and available experiments is satisfactory except in the high temperature end of the spectrum. The current results indicate that above 1100 K He migration is assisted by lattice defects such as vacancies, rather than through interstitial diffusion.


PACS

66.30.Lw Diffusion of other defects

68.43.Mn Adsorption kinetics

61.72.J- Point defects and defect clusters

64.75.-g Phase equilibria

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 33 (19 August 2009)

Received 17 March 2009, in final form 3 June 2009

Published 24 July 2009



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