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Structure and ferroelectric properties of epitaxial (1−x)BiFeO3xBaTiO3 solid solution films

P Murugavel1, J-H Lee2, J Y Jo2, Hye Yeong Sim2, J-S Chung3, Younghun Jo4 and Myung-Hwa Jung4

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We fabricated epitaxial (1−x)BiFeO3xBaTiO3 (x = 0.1–0.7) solid solution films on niobium doped SrTiO3(001) substrate. The x-ray diffraction analysis of the films indicates compressively strained growth for the composition x<0.3 and strain relaxed growth for the composition x≥0.3. Correspondingly, the films showed a structural change from a rhombohedral (or modified monoclinic MA) phase to a tetragonal phase near the composition x~0.3. Interestingly the ferroelectric measurements showed a distinct difference between the compositions, with the boundary at x~0.3, above which the films remain in a highly resistive state. The magnetic measurements revealed a weak ferromagnetic signature for the films of composition x≤0.5.


PACS

68.55.-a Thin film structure and morphology

68.55.Nq Composition and phase identification

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

68.55.A- Nucleation and growth

77.22.Ej Polarization and depolarization

81.15.Fg Laser deposition

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 41 (15 October 2008)

Received 11 December 2007, in final form 2 August 2008

Published 12 September 2008



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