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Magnetic moments, exchange coupling, and crossover temperatures of Co clusters on Pt(111) and Au(111)

O Šipr1, S Bornemann2, J Minár2, S Polesya2, V Popescu2,3, A Šimůnek1 and H Ebert2

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The influence of cluster size and of cluster–substrate interaction on the magnetic properties of Co clusters of 1–10 atoms on Pt(111) and Au(111) is studied by fully relativistic ab initio calculations. The focus is on systematic trends of the spin and orbital magnetic moments, the exchange coupling, and the crossover temperature. The spin magnetic moments of Co clusters are larger for the Pt substrate than for the Au substrate, while the reverse is true for the orbital magnetic moments. The local magnetic moments of Co atoms generally increase if the number of Co neighbours decreases. The exchange coupling constants Jij depend on the cluster size and on the location of respective atoms. The crossover temperature increases monotonically with cluster size and is larger for clusters on Pt than for clusters on Au.


PACS

75.30.Cr Saturation moments and magnetic susceptibilities

75.75.+a Magnetic properties of nanostructures

73.22.-f Electronic structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals

75.30.Et Exchange and superexchange interactions

73.20.At Surface states, band structure, electron density of states

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 9 (7 March 2007)

Received 20 November 2006, in final form 22 December 2006

Published 14 February 2007



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