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One-dimensional Au on TiO2

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A Locatelli1, T Pabisiak2, A Pavlovska3, T O Mentes1, L Aballe1, A Kiejna2 and E Bauer1,3

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One-dimensional Au rows are produced on the TiO2(110) surface by controlled photon-stimulated desorption followed by Au deposition at 750 K. In the resulting (1 × 2) structure, O vacancies are replaced by Au atoms, as demonstrated by combined laterally resolved x-ray spectroscopy and micro-LEED (low-energy electron diffraction) measurements. The experimental results are confirmed by first-principles calculations, which indicate strong Au–Ti bonding and a very stable configuration of the Au rows. The calculations determine the detailed atomic structure of the Au rows, with an inter-row spacing of 13 Å and an intra-row Au distance of 2.95 Å.


PACS

68.43.Tj Photon stimulated desorption

68.35.Dv Composition, segregation; defects and impurities

68.43.Mn Adsorption kinetics

79.60.Dp Adsorbed layers and thin films

61.05.jh Low-energy electron diffraction (LEED) and reflection high-energy electron diffraction (RHEED)

79.20.La Photon- and electron-stimulated desorption

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 8 (28 February 2007)

Received 2 January 2007

Published 6 February 2007



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