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Anharmonic effects in single-walled carbon nanotubes

Kun Gao1, Rucheng Dai1, Zengming Zhang2 and Zejun Ding1,3,4

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We have investigated the temperature and excitation energy dependence of Raman spectra of single-wall carbon nanotubes (SWCNTs). The measured Raman shifts for D and G bands of SWCNTs show a softening behavior upon increasing temperature (83–733 K). A theoretical model is developed to study the frequency shifts for these two Raman modes as a function of temperature; the calculated results agree well with the experimental data. The calculation indicates that the virtual optical-phonon couplings dominate contributions to the temperature variance of frequency shifts for D and G bands of SWCNTs while the pure-volume effect is very weak. Measurements of peak positions and linewidths of D and G bands are also carried out at three different excitation wavelengths (325, 514.5 and 785 nm). It is found that not only does the peak position of the D band exhibit a linear increase, but also the linewidth of the G band does upon increasing excitation energy. In addition, we also measure the relative intensity ratios of the D band to the G band (ID/IG) with temperature and excitation energy in this work.


PACS

63.22.-m Phonons or vibrational states in low-dimensional structures and nanoscale materials

78.67.Ch Nanotubes

78.30.Hv Other nonmetallic inorganics

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 48 (5 December 2007)

Received 29 June 2007, in final form 22 October 2007

Published 9 November 2007



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