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Ab initio lattice dynamics of zinc-blende GaxIn1−xN alloys

S Saib1,3, N Bouarissa2,4, P Rodríguez-Hernández1 and A Muñoz1

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Using ab initio calculations in the framework of plane-wave pseudopotential implementation of the density-functional theory within the local density approximation under the virtual crystal approximation, we present a theoretical study of the elastic and dielectric properties and zone-center optical phonons in zinc-blende GaxIn1−xN alloys over the whole composition range from pure InN to pure GaN. The computed values are generally in reasonably good agreement with the existing experimental data for both parent compounds InN and GaN and provide predictions for GaxIn1−xN in the composition range 0–1 (0<x<1). The compositional dependence of the elastic constants, Born effective charge, high-frequency dielectric constant and vibration modes was investigated.


PACS

62.20.D- Elasticity

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

71.15.Ap Basis sets (LCAO, plane-wave, APW, etc.) and related methodology (scattering methods, ASA, linearized methods, etc.)

81.40.Jj Elasticity and anelasticity, stress-strain relations

63.20.-e Phonons in crystal lattices

77.22.Ch Permittivity (dielectric function)

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 48 (5 December 2007)

Received 15 July 2007, in final form 21 October 2007

Published 9 November 2007



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