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Modification of medium-range order in silica glass by ball-milling: real- and reciprocal-space structural correlations for the first sharp diffraction peak

Akira Mukai1, Shinji Kohara2 and Takashi Uchino1

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We have carried out high-energy x-ray diffraction measurements on mechanically milled silica glass. It has been found that the first sharp diffraction peak (FSDP) in the structure factor S(Q) of silica glass appreciably decreases in intensity as a result of mechanical milling, whereas the observed features of the other peaks in S(Q) almost remain unchanged. The corresponding real-space correlation function of the milled samples shows a marked decrease in intensity at r~5 Å. This gives an experimental manifestation that the dominant real-space structural correlation pertaining to the FSDP occurs at r~5 Å.


PACS

61.43.Fs Glasses

81.20.Wk Machining, milling

61.05.cp X-ray diffraction

Subjects

Condensed matter: structural, mechanical & thermal

Dates

Issue 45 (14 November 2007)

Received 1 August 2007, in final form 2 August 2007

Published 24 October 2007



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