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Short- and intermediate-range order in levitated liquid aluminates

L Hennet1, I Pozdnyakova1, V Cristiglio1,2, G J Cuello2, S Jahn3, S Krishnan4, M-L Saboungi5 and D L Price1

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We have used the aerodynamic levitation technique combined with CO2 laser heating to study the structures of liquid CaAl2O4 and MgAl2O4 with x-ray and neutron diffraction. We determined the structure factors and corresponding pair correlation functions describing the short- and intermediate-range order in the liquids. The combination of the two scattering techniques makes it possible to derive information not accessible with a single measurement. In the case of the glass-forming liquid CaAl2O4 we have made sequential measurements during free cooling to study the structural evolution during supercooling from the stable liquid phase to the cold glass below Tg.


PACS

61.25.-f Studies of specific liquid structures

64.70.D- Solid–liquid transitions

61.05.fm Neutron diffraction

61.05.cp X-ray diffraction

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Dates

Issue 45 (14 November 2007)

Received 5 August 2007

Published 24 October 2007



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