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Competition between glass transition and liquid–gas separation in attracting colloids

A M Puertas1, M Fuchs2 and M E Cates3

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We present simulation results addressing the phenomenon of colloidal gelation induced by attractive interactions. The liquid–gas transition is prevented by the glass arrest at high enough attraction strength, resulting in a colloidal gel. The dynamics of the system is controlled by the glass, with little effect of the liquid–gas transition. When the system separates into liquid and vapour phases, even if the denser phase enters the non-ergodic region, the vapour phase enables the structural relaxation of the system as a whole.


PACS

64.70.P- Glass transitions of specific systems

64.75.-g Phase equilibria

64.70.F- Liquid–vapor transitions

82.70.Dd Colloids

82.70.Gg Gels and sols

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 20 (23 May 2007)

Received 2 January 2007

Published 25 April 2007



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