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Short- and long-range correlated motion observed in colloidal glasses and liquids

Eric R Weeks1, John C Crocker2 and D A Weitz3

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We use a confocal microscope to examine the motion of individual particles in a dense colloidal suspension. Close to the glass transition, particle motion is strongly spatially correlated. The correlations decay exponentially with particle separation, yielding a dynamic length scale of O(2–3σ) (in terms of particle diameter σ). This length scale grows modestly as the glass transition is approached. Further, the correlated motion exhibits a strong spatial dependence on the pair correlation function g(r). Motion within glassy samples is weakly correlated, but with a larger spatial scale for this correlation.


PACS

82.70.Dd Colloids

61.20.-p Structure of liquids

61.43.Fs Glasses

82.70.Kj Emulsions and suspensions

66.20.-d Viscosity of liquids; diffusive momentum transport

64.70.P- Glass transitions of specific systems

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 20 (23 May 2007)

Received 6 October 2006

Published 25 April 2007



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