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Anisotropic spatially heterogeneous dynamics in a model glass-forming binary mixture

Elijah Flenner1 and Grzegorz Szamel

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We calculated a four-point correlation function G_4(\vec {k},\vec {r};t) and the corresponding structure factor S_4(\vec {k},\vec {q};t) for a model glass-forming binary mixture. These functions measure the spatial correlations of the relaxation of different particles. We found that these four-point functions are anisotropic and depend on the angle between vectors \vec {k} and \vec {r} (or \vec {q} ). The anisotropy is the strongest for times somewhat longer than the β relaxation time, but it is quite pronounced even for times comparable to the α relaxation time, τα. At the lowest temperatures S_4(\vec {k},\vec {q};\tau_{\alpha }) is strongly anisotropic even for the smallest wavevector q accessible in our simulation.


PACS

61.20.Lc Time-dependent properties; relaxation

61.20.Gy Theory and models of liquid structure

64.70.P- Glass transitions of specific systems

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Dates

Issue 20 (23 May 2007)

Received 9 October 2006

Published 25 April 2007



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