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Ferromagnetism and infrared conductivity of the homogeneous hexaboride alloy Eu1−xCaxB6

Jungho Kim1, SungHoon Jung2, J H Noh2, B K Cho3 and E J Choi2,4

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We have studied the magnetic and optical properties of hexaboride Eu1−xCaxB6 for x = 0, 0.13, 0.25, 0.35, 0.54 and 1.0 from measurements of dc magnetization and wide-range absolute reflectivity. The ferromagnetic transition temperature Tc decreases with Ca-doping and is completely suppressed when x exceeds 0.35. The Drude plasma frequency ωp2 also decreases with x and disappears at the same composition. We have analysed this correlation between Tc and ωp2 in terms of the RKKY theory. We have also simulated optical spectra of Eu1−xCaxB6 using the effective medium theory and compare them with the measured data. The results show that Eu1−xCaxB6 is not a composite of EuB6 and CaB6 but forms a homogeneous magnetic alloy.


PACS

78.20.Ci Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

75.50.Cc Other ferromagnetic metals and alloys

75.30.Et Exchange and superexchange interactions

Subjects

Condensed matter: electrical, magnetic and optical

Dates

Issue 10 (14 March 2007)

Received 5 October 2006, in final form 24 January 2007

Published 15 February 2007



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