José Teixeira et al 2006 J. Phys.: Condens. Matter 18 S2353 doi:10.1088/0953-8984/18/36/S09
José Teixeira1, Alenka Luzar2 and Stéphane Longeville1
Show affiliationsThe dynamics of hydrogen bonds between water molecules is probed by means of coherent quasielastic neutron scattering. The choice of appropriate values of the momentum transfer gives information about the time dependence of the DD partial of the scattering function of D2O. Experimental results demonstrate that the temperature dependence of the dynamics of hydrogen bonds is weak, in contrast with that of the transport properties of liquid water. We discuss our results in view of a recent application of mode coupling theory to describe the dynamics in polymer melts (Richter et al 1998 Physica B 241–243 1005). In particular, we give arguments in favour of a normal (Arrhenius) temperature dependence of hydrogen bond dynamics at extremely low temperatures. We relate this dynamics to β relaxation. This is in contrast to what happens with polymer gels, where the α processes, related to backbone movement, block the molecular motions. The anomalous (non-Arrhenius) temperature dependence of the transport properties of water is therefore due to the increased number of hydrogen bonds, rather then to their intrinsic dynamics, which remains fast.
66.20.-d Viscosity of liquids; diffusive momentum transport
61.25.H- Macromolecular and polymers solutions; polymer melts
61.05.fg Neutron scattering (including small-angle scattering)
Issue 36 (13 September 2006)
Received 6 February 2006
Published 24 August 2006
José Teixeira et al 2006 J. Phys.: Condens. Matter 18 S2353
Hans J Scheer et al 2006 Physiol. Meas. 27 109
Lior M Burko 2006 Class. Quantum Grav. 23 4281
Lior M Burko 1999 Eur. J. Phys. 20 281
Lior M Burko 2003 Eur. J. Phys. 24 125
G Baramidze and G Kharadze 2002 J. Phys.: Condens. Matter 14 7471
N A Greaves 1976 J. Phys. C: Solid State Phys. 9 L181
Emily Rauscher et al. 2008 ApJ 681 1646
F. Elliott Koch and Bradley M. S. Hansen 2008 ApJ 687 252
Brad M. S. Hansen et al. 2007 ApJ 671 380