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Principles of operating molecular nanomachines by electronic excitation

Geneviève Comtet, Gérald Dujardin, Andrew J Mayne and Damien Riedel

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Powering and controlling the operation of a single molecule adsorbed on a surface can be achieved by using the tip of a scanning tunnelling microscope (STM) as an atomic-size source of electrons. We review the various electronic excitation processes induced by the electrons from the STM tip which are able to activate the functions of a molecular nanomachine. In particular, we review recent results illustrating the electronic control of molecular dynamics at the level of a single molecule.


PACS

68.43.Mn Adsorption kinetics

68.47.Fg Semiconductor surfaces

79.60.Dp Adsorbed layers and thin films

73.20.Hb Impurity and defect levels; energy states of adsorbed species

68.37.Ef Scanning tunneling microscopy (including chemistry induced with STM)

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Dates

Issue 33 (23 August 2006)

Received 12 January 2006

Published 4 August 2006



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