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Training effects in Gd5Ge4: role of microstructure

Meghmalhar Manekar1, M K Chattopadhyay1, R Kaul2, V K Pecharsky3,4 and K A Gschneidner Jr3,4

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Detailed optical metallographic studies at room temperature on polycrystalline Gd5Ge4 are presented for two cases: (a) a sample in the as-cast condition and (b) the same sample subjected to a known number of temperature and magnetic field cycles. A herringbone- (criss-cross-) like pattern whose characteristic feature size extends to ≈20 µm is observed in the as-cast sample. The herringbone pattern at room temperature is interpreted as arising due to a long-lived (kinetically arrested) metastable phase. This herringbone pattern can be trained to form a pattern having a different morphology by cycling the sample through the low-temperature field induced magneto-structural transition. Training effects are also observed in magneto-transport and magnetization measurements as the sample is subjected to temperature and field cycles. Based on heuristic arguments, a model is proposed which self-consistently explains anomalies in transport and magnetization properties in terms of changes occurring in the microstructure of the sample. These results highlight the need for analysing the interesting properties of Gd5Ge4 and its family of alloys with microstructure as an important component.


PACS

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

61.66.Dk Alloys

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

61.50.Ks Crystallographic aspects of phase transformations; pressure effects

75.30.Sg Magnetocaloric effect, magnetic cooling

76.50.+g Ferromagnetic, antiferromagnetic, and ferrimagnetic resonances; spin-wave resonance

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 26 (5 July 2006)

Received 18 January 2006, in final form 27 April 2006

Published 19 June 2006



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