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Diamond-anvil cell for radial x-ray diffraction

G N Chesnut, D Schiferl, B D Streetman and W W Anderson

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We have designed a new diamond-anvil cell capable of radial x-ray diffraction to pressures of a few hundred GPa. The diffraction geometry allows access to multiple angles of Ψ, which is the angle between each reciprocal lattice vector g(hkl) and the compression axis of the cell. At the 'magic angle', Ψ≈54.7°, the effects of deviatoric stresses on the interplanar spacings, d(hkl), are significantly reduced. Because the systematic errors, which are different for each d(hkl), are significantly reduced, the crystal structures and the derived equations of state can be determined reliably. At other values of Ψ, the effects of deviatoric stresses on the diffraction pattern could eventually be used to determine elastic constants.


PACS

61.05.cp X-ray diffraction

62.50.-p High-pressure effects in solids and liquids

62.20.F- Deformation and plasticity

61.66.Bi Elemental solids

62.20.D- Elasticity

Subjects

Condensed matter: structural, mechanical & thermal

Dates

Issue 25 (28 June 2006)

Received 14 January 2006, in final form 20 March 2006

Published 8 June 2006



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