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Effect of shear strain on the α–ε phase transition of iron: a new approach in the rotational diamond anvil cell

Yanzhang Ma, Emre Selvi, Valery I Levitas and Javad Hashemi

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The effect of shear strain on the iron α–ε phase transformation has been studied using a rotational diamond anvil cell (RDAC). The initial transition is observed to take place at the reduced pressure of 10.8 GPa under pressure and shear operation. Complete phase transformation was observed at 15.4 GPa. The rotation of an anvil causes limited pressure elevation and makes the pressure distribution symmetric in the sample chamber before the phase transition. However, it causes a significant pressure increase at the centre of the sample and brings about a large pressure gradient during the phase transformation. The resistance to the phase interface motion is enhanced due to strain hardening during the pressure and shear operations on iron and this further increases the transition pressure. The work of macroscopic shear stress and the work of the pressure and shear stress at the defect tips account for the pressure reduction of the iron phase transition.


PACS

64.70.K- Solid–solid transitions

61.05.cp X-ray diffraction

62.20.-x Mechanical properties of solids

81.40.Jj Elasticity and anelasticity, stress-strain relations

62.50.-p High-pressure effects in solids and liquids

Subjects

Condensed matter: structural, mechanical & thermal

Dates

Issue 25 (28 June 2006)

Received 1 December 2005, in final form 24 March 2006

Published 8 June 2006



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