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Polar optical phonons in wurtzite spheroidal quantum dots: theory and application to ZnO and ZnO/MgZnO nanostructures

Vladimir A Fonoberov and Alexander A Balandin

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Polar optical-phonon modes are derived analytically for spheroidal quantum dots with wurtzite crystal structure. The developed theory is applied to freestanding spheroidal ZnO quantum dots and to spheroidal ZnO quantum dots embedded into a MgZnO crystal. The wurtzite (anisotropic) quantum dots are shown to have strongly different polar optical-phonon modes in comparison with zincblende (isotropic) quantum dots. The obtained results allow one to explain and accurately predict phonon peaks in the Raman spectra of wurtzite nanocrystals, nanorods (prolate spheroids), and epitaxial quantum dots (oblate spheroids).


PACS

68.65.Hb Quantum dots (patterned in quantum wells)

78.30.-j Infrared and Raman spectra

78.67.Hc Quantum dots

61.66.Fn Inorganic compounds

63.22.-m Phonons or vibrational states in low-dimensional structures and nanoscale materials

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 7 (23 February 2005)

Received 10 December 2004, in final form 12 January 2005

Published 4 February 2005



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