Changmei Zhao et al 2005 J. Phys.: Condens. Matter 17 S2841 doi:10.1088/0953-8984/17/31/009
Sliding mode of cyclodextrin in polyrotaxane and slide-ring gel
Changmei Zhao1, Yusuke Domon1, Yasushi Okumura1,3, Satoshi Okabe2, Mitsuhiro Shibayama2 and Kohzo Ito1,3
Show affiliationsThe sliding modes of cyclic molecules in polyrotaxane and of cross-linking junctions in topological gel or slide-ring gel were investigated by quasi-elastic light scattering. We found that a polyrotaxane sparsely including α-cyclodextrin showed the sliding mode in solution other than the self- and cooperative-diffusion modes whereas the sliding mode was not observed in a polyrotaxane densely including α-cyclodextrin. After gelation of the sparse polyrotaxane, the self-diffusion mode of the polyrotaxane disappeared but the sliding mode was still observed. This indicated that the figure-of-eight cross-links in the slide-ring gel slid in the polymer network, passing through the polymer chains.
- PACS
-
66.10.C- Diffusion and thermal diffusion
78.35.+c Brillouin and Rayleigh scattering; other light scattering
61.25.H- Macromolecular and polymers solutions; polymer melts
- Subjects
-
Soft matter, liquids and polymers
- Dates
-
Issue 31 (10 August 2005)
Received 10 June 2005
Published 22 July 2005
-
Sliding mode of cyclodextrin in polyrotaxane and slide-ring gel
Changmei Zhao et al 2005 J. Phys.: Condens. Matter 17 S2841
-
A Monte Carlo study of leading order scaling corrections of
4 theory on a three-dimensional lattice
M Hasenbusch 1999 J. Phys. A: Math. Gen. 32 4851
-
Intensity Correlation Function of Light Scattering from a Weakly One-Dimensional Random Rough Surface
Wu Zhen-Sen and Zhang Geng 2009 Chinese Phys. Lett. 26 114208
-
Evaluation of Appell functions in relativistic Coulomb-Dirac form factors
U Becker et al 1987 J. Phys. A: Math. Gen. 20 5447
-
Observation of exceptional points in electronic circuits
T Stehmann et al 2004 J. Phys. A: Math. Gen. 37 7813
-
Cerenkov radiation by a point charge moving parallel to the plane interface between two semi-infinite dielectric media
R M Khan 1967 Br. J. Appl. Phys. 18 1443
-
Specific heat and entropy of GaN
M Sanati and S K Estreicher 2004 J. Phys.: Condens. Matter 16 L327
-
Burst wave analysis of TAMA300 data with the ALF filter
T Akutsu et al 2005 Class. Quantum Grav. 22 S1303
-
Rindler particles and classical radiation
D E Díaz and J Stephany 2002 Class. Quantum Grav. 19 3753
-
Cooling of Accelerated Nucleons and Neutrino Emission in Gamma-Ray Bursts
Katsuaki Asano 2005 ApJ 623 967
Related review articles
What's this?- Non-equilibrium magnetic colloidal dispersions at liquid–air interfaces: dynamic patterns, magnetic order and self-assembled swimmers
- Colloids as model systems for metals and alloys: a case study of crystallization
- Crystallization in three- and two-dimensional colloidal suspensions