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The single-phase multiferroic oxides: from bulk to thin film

REVIEW ARTICLE

W Prellier, M P Singh and P Murugavel

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TOPICAL REVIEW

Complex perovskite oxides exhibit a rich spectrum of properties, including magnetism, ferroelectricity, strongly correlated electron behaviour, superconductivity and magnetoresistance, which have been research areas of great interest among the scientific and technological community for decades. There exist very few materials which exhibit multiple functional properties; one such class of materials is called the multiferroics. Multiferroics are interesting because they exhibit simultaneously ferromagnetic and ferroelectric polarizations and a coupling between them. Due to the nontrivial lattice coupling between the magnetic and electronic domains (the magnetoelectric effect), the magnetic polarization can be switched by applying an electric field; likewise the ferroelectric polarization can be switched by applying a magnetic field. As a consequence, multiferroics offer rich physics and novel devices concepts, which have recently become of great interest to researchers. In this review article the recent experimental status, for both the bulk single phase and the thin film form, has been presented. Current studies on the ceramic compounds in the bulk form including Bi(Fe,Mn)O3, REMnO3 andthe series of REMn2O5 single crystals (RE =  rare earth) are discussed in the first section and a detailed overview on multiferroic thin films grown artificially (multilayers and nanocomposites) is presented in the second section.


PACS

77.22.Ej Polarization and depolarization

77.55.+f Dielectric thin films

75.80.+q Magnetomechanical and magnetoelectric effects, magnetostriction

77.80.Dj Domain structure; hysteresis

75.70.Ak Magnetic properties of monolayers and thin films

75.70.Kw Domain structure (including magnetic bubbles)

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 30 (3 August 2005)

Received 22 February 2005, in final form 7 June 2005

Published 15 July 2005


A Corrigendum for this article has been published in 2005 J. Phys.: Condens. Matter 17 7753


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