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Viscoelastic properties of attractive and repulsive colloidal glasses

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Antonio M Puertas1, Emanuela Zaccarelli2 and Francesco Sciortino2

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LETTER TO THE EDITOR

We report a numerical study of the shear viscosity and the frequency dependent elastic moduli close to dynamical arrest for a model of short range attractive colloids, both for the repulsive and the attractive glass transition. Calculating the stress autocorrelation functions, we find that density fluctuations of wavevectors close to the first peak in the structure factor control the viscosity rise on approaching the repulsive glass, while fluctuations of larger wavevectors control the viscosity close to the attractive glass. On approaching the glass transition, the viscosity diverges with a power law with the same exponent as the density autocorrelation time.


PACS

47.57.J- Colloidal systems

66.20.-d Viscosity of liquids; diffusive momentum transport

62.40.+i Anelasticity, internal friction, stress relaxation, and mechanical resonances

64.70.P- Glass transitions of specific systems

62.10.+s Mechanical properties of liquids

82.70.Dd Colloids

Subjects

Soft matter, liquids and polymers

Fluid dynamics

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 25 (29 June 2005)

Received 15 March 2005, in final form 15 May 2005

Published 10 June 2005



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