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Electronic density of states in amorphous selenium

M L Benkhedir, M Brinza and G J Adriaenssens

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Steady-state and transient photoconductivity methods are used to investigate the electronic density of states in evaporated layers of amorphous selenium. From the temperature dependence of the steady-state photocurrent and, independently, from an analysis of the post-transit currents of time-of-flight transients, energy levels in the gap at 1.43 ± 0.02 eV and 0.40 ± 0.02 eV above the valence band have been determined for the occupied state of the negative-U centres. An absorption band around 1.50 eV is seen in the spectral distribution of the photocurrent. The distribution of tail states may—to first approximation—be described by a steep exponential with a characteristic width of {\sim
}24  meV at the valence band and a more steeply declining functional of similar width at the conduction band.


PACS

72.40.+w Photoconduction and photovoltaic effects

71.23.Cq Amorphous semiconductors, metallic glasses, glasses

73.50.Pz Photoconduction and photovoltaic effects

73.61.Jc Amorphous semiconductors; glasses

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Dates

Issue 44 (10 November 2004)

Received 14 August 2004

Published 22 October 2004



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