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The understanding of electronic excitations of C60 on graphite

M F Luo1,2, Z Y Li3,4 and W Allison1

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Electron energy loss spectroscopy has been used to probe the coverage-dependent electronic excitations from a C60 covered graphite surface. In the energy region corresponding to the optical band-gap of the bulk C60 solid, the dipole-scattering contribution to the loss features is simulated by a double dielectric layer model. We find that a good agreement between the simulated spectra and the experimental results can be achieved for a C60 multilayer. However, an additional energy loss channel is required in order to describe the electronic excitations for a C60 monolayer. The possible significances of this finding are discussed.


PACS

68.49.Jk Electron scattering from surfaces

71.45.Gm Exchange, correlation, dielectric and magnetic response functions, plasmons

78.20.Ci Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)

71.20.Tx Fullerenes and related materials; intercalation compounds

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 34 (1 September 2004)

Received 30 May 2004

Published 13 August 2004



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