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Specific heat and entropy of GaN

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M Sanati and S K Estreicher

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LETTER TO THE EDITOR

The specific heat and entropy of (wurtzite) GaN are not well known experimentally. The literature values for Cp (T>298 K) are based on a fit to an analytic function. The parameters include Cp (298 K) and the melting temperature Tm, both of which were poorly known when the parameters were first determined. The value of Cp (298 K) disagrees with the data measured in the range 5–305 K. Our first-principles calculations allow the values of the parameters to be established and lead to a more accurate prediction of specific heat and entropy of GaN.


PACS

65.40.Ba Heat capacity

65.40.G- Other thermodynamical quantities

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 28 (21 July 2004)

Received 17 May 2004

Published 2 July 2004



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