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Phase transitions, partial disorder and multi-k structures in Gd2Ti2O7

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J R Stewart1, G Ehlers2, A S Wills3, S T Bramwell3 and J S Gardner4,5

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LETTER TO THE EDITOR

The geometrically frustrated antiferromagnet Gd2Ti2O7 exhibits magnetic behaviour of such complexity that it poses a challenge to both experiment and theory. Magnetic ordering commences at TN = 1.1 K and there is a further magnetic phase transition at T^{\prime }=0.7  K. Here we use neutron diffraction to definitively establish the nature of the phase transition at T^{\prime } and the magnetic structure adopted below this temperature. Between T^{\prime
} and TN the structure is partly ordered, as previously reported. Below T^{\prime } the remaining spins order, but only weakly. The magnetic structure in this temperature range is shown to be a 4-k structure, closely related to the 1-k structure previously suggested. The 4-k and 1-k variants of the structure are distinguished by analysis of the diffuse scattering, which we believe represents a new method of solving the 'multi-k' problem of magnetic structure determination.


PACS

75.50.Ee Antiferromagnetics

61.05.fg Neutron scattering (including small-angle scattering)

75.25.+z Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source x-ray scattering, etc.)

61.05.fm Neutron diffraction

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

75.30.Wx Spin crossover

Subjects

Condensed matter: electrical, magnetic and optical

Dates

Issue 28 (21 July 2004)

Received 12 March 2004

Published 2 July 2004



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