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Structural and electronic properties of epitaxial V2O3 thin films

B Sass1, C Tusche1, W Felsch1, N Quaas2, A Weismann2 and M Wenderoth2

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Thin films of V2O3 with thickness 4–300 nm were grown on (11\bar {2}0) -oriented sapphire substrates by reactive dc magnetron sputtering. X-ray diffraction, pole figure measurements and scanning tunnelling microscopy show high crystallinity and epitaxy to the substrate with a faceted surface structure, and the absence of strain. Measurements of the electrical resistivity, scanning tunnelling and x-ray absorption spectroscopy show a metal–insulator transition near 150 K that is connected with the opening of an energy gap and a characteristic modification of the absorption spectrum at the vanadium-2p and oxygen-1s edges. These observations reveal that the {\mathrm {V_2O_3}} (11\bar {2}0) films have bulk-like properties.


PACS

68.55.-a Thin film structure and morphology

81.15.Cd Deposition by sputtering

68.37.Ef Scanning tunneling microscopy (including chemistry induced with STM)

78.66.Nk Insulators

71.30.+h Metal-insulator transitions and other electronic transitions

68.35.B- Structure of clean surfaces (and surface reconstruction)

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Dates

Issue 1 (14 January 2004)

Received 23 October 2003

Published 15 December 2003



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