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A quantitative measure of medium-range order in amorphous materials from transmission electron micrographs

R K Dash1, P M Voyles2, J M Gibson3, M M J Treacy4 and P Keblinski1

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We propose an extension to the technique of fluctuation electron microscopy that quantitatively measures a medium-range order correlation length in amorphous materials. In both simulated images from computer-generated paracrystalline amorphous silicon models and experimental images of amorphous silicon, we find that the spatial autocorrelation function of dark-field transmission electron micrographs of amorphous materials exhibits a simple exponential decay. The decay length measures a nanometre-scale structural correlation length in the sample, although it also depends on the microscope resolution. We also propose a new interpretation of the fluctuation microscopy image variance in terms of fluctuations in local atomic pair distribution functions.


PACS

61.43.Bn Structural modeling: serial-addition models, computer simulation

02.70.Dh Finite-element and Galerkin methods

Subjects

Computational physics

Condensed matter: structural, mechanical & thermal

Dates

Issue 31 (13 August 2003)

Received 20 May 2003

Published 23 July 2003



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