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Disjoining pressure in thin liquid foam and emulsion films—new concepts and perspectives

REVIEW ARTICLE

Cosima Stubenrauch1,3 and Regine von Klitzing2

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TOPICAL REVIEW

The present review is a topical survey of the disjoining pressure in thin liquid foam and emulsion films from both the experimental and the theoretical points of view. Section 2 deals with the latest research work on experimental techniques with which the disjoining pressure Π in foam, emulsion, and pseudo-emulsion films can be measured. Although a lot of techniques are available, the question of the origin of the charges at the water/air and the water/oil interfaces of films, which are stabilized by non-ionic surfactants, has not yet been answered. We address this question in section 3, reviewing the latest relevant literature. The relevance of structural forces for the disjoining pressure is outlined in section 4, which focuses on films which are stabilized by surfactant/polyelectrolyte mixtures.


PACS

68.15.+e Liquid thin films

68.05.-n Liquid-liquid interfaces

82.70.Kj Emulsions and suspensions

82.70.Uv Surfactants, micellar solutions, vesicles, lamellae, amphiphilic systems, (hydrophilic and hydrophobic interactions)

68.03.-g Gas-liquid and vacuum-liquid interfaces

82.70.Rr Aerosols and foams

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Chemical physics and physical chemistry

Dates

Issue 27 (16 July 2003)

Received 3 December 2002

Published 27 June 2003



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