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Soft magnetic nanoparticles of BaFe12O19 fabricated under mild conditions

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Shan Che, Jun Wang and Qianwang Chen1

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LETTER TO THE EDITOR

Nanoparticles of barium hexaferrite, with an average size of 12 nm, were prepared by a hydrothermal route at relatively low temperatures (140–180 °C). The effects of reaction temperature and time on the particle size and magnetic properties were discussed. The nanoparticles show a soft magnetic feature with a saturation magnetization of 1.1 emu g−1 and coercivity of 221.0 Oe, rather than the hard magnetic characteristic that the corresponding bulk material exhibits. Annealing treatment in air at 800 °C led to an order-of-magnitude increase of the saturation magnetization (67.3 emu g−1) and coercive force (4511 Oe). It is suggested that the oxygen vacancies should be responsible for the soft magnetic characteristic that appeared for the as-prepared barium hexaferrite nanoparticles.


PACS

75.50.Tt Fine-particle systems; nanocrystalline materials

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

81.16.Be Chemical synthesis methods

Subjects

Condensed matter: electrical, magnetic and optical

Nanoscale science and low-D systems

Dates

Issue 22 (11 June 2003)

Received 30 April 2003

Published 23 May 2003



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