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Magneto-optical transitions in multilayer semiconductor nanocrystals

J Climente1, J Planelles1, W Jaskólski2 and J I Aliaga3

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Absorption spectra of chemically synthesized uniform and multilayer semiconductor nanocrystals in a magnetic field are investigated theoretically. The nanocrystals are modelled by spherical barrier/well potentials. The electron states are calculated within the effective mass model. A four-band k centerdot p Hamiltonian, accounting for the valence subband mixing, is used to obtain the hole states. The magneto-optical transition spectrum depends strongly on the size and composition of the nanocrystals. In the case of small uniform quantum dots, only the linear Zeeman splitting of the electron and hole energy levels is observed even for very strong magnetic fields. In larger nanocrystals, the quadratic magnetic interaction turns out to be important and the transition spectrum becomes complicated. The most complicated influence of the magnetic field is found in quantum dot–quantum well systems in which the lowest electron and hole states are localized in a thin spherical layer. It is shown that transitions that are optically active when no magnetic field is applied remain strong even in very strong fields.


PACS

68.65.Ac Multilayers

71.70.Ej Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect

71.18.+y Fermi surface: calculations and measurements; effective mass, g factor

75.50.Pp Magnetic semiconductors

78.67.Bf Nanocrystals and nanoparticles

64.70.Nd Structural transitions in nanoscale materials

78.67.Hc Quantum dots

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 21 (4 June 2003)

Received 6 February 2003, in final form 31 March 2003

Published 19 May 2003



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