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Correlated dewetting patterns in thin polystyrene films

Chiara Neto1, Karin Jacobs1,4, Ralf Seemann1, Ralf Blossey2, Jürgen Becker3 and Günther Grün3

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We describe preliminary results of experiments and simulations concerned with the dewetting of thin polystyrene films (thickness < 7 nm) on top of silicon oxide wafers. In the experiments we scratched an initially flat film with an atomic force microscopy (AFM) tip, producing dry channels in the film. Dewetting of the films was imaged in situ using AFM and a correlated pattern of holes ('satellite holes') was observed along the rims bordering the channels. The development of this complex film rupture process was simulated and the results of experiments and simulations are in good agreement. On the basis of these results, we attempt to explain the appearance of satellite holes and their positions relative to pre-existing holes.


PACS

68.55.-a Thin film structure and morphology

62.20.M- Structural failure of materials

68.08.Bc Wetting

81.40.Np Fatigue, corrosion fatigue, embrittlement, cracking, fracture, and failure

68.37.Ps Atomic force microscopy (AFM)

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 1 (15 January 2003)

Received 24 October 2002

Published 16 December 2002



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