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Control of colloids with gravity, temperature gradients, and electric fields

Matt Sullivan1, Kun Zhao1, Christopher Harrison1, Robert H Austin1, Mischa Megens1, Andrew Hollingsworth2, William B Russel2, Zhengdong Cheng3, Thomas Mason3 and P M Chaikin1,3

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We have used a variety of different applied fields to control the density, growth, and structure of colloidal crystals. Gravity exerts a body force proportional to the buoyant mass and in equilibrium produces a height-dependent concentration profile. A similar body force can be obtained with electric fields on charged particles (electrophoresis), a temperature gradient on all particles, or an electric field gradient on uncharged particles (dielectrophoresis). The last is particularly interesting since its magnitude and sign can be changed by tuning the applied frequency. We study these effects in bulk (making 'dielectrophoretic bottles' or traps), to control concentration profiles during nucleation and growth and near surfaces. We also study control of non-spherical and optically anisotropic particles with the light field from laser tweezers.


PACS

82.70.Dd Colloids

82.45.-h Electrochemistry and electrophoresis

Subjects

Soft matter, liquids and polymers

Chemical physics and physical chemistry

Dates

Issue 1 (15 January 2003)

Received 16 October 2002

Published 16 December 2002



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