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Material design from first principles: the case of boron nitride polymers

Michel Côté1, Peter D Haynes2 and Carla Molteni2,3

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In recent years, first-principles quantum-mechanical simulations have become established as a complementary tool to experiments in the design and characterization of new materials. Here we illustrate this in the case of boron nitride (BN) analogues of conjugated organic polymers which offer a cheap alternative to inorganic semiconductors in the manufacture of electronic devices. By analogy with heterostructures, such as quantum wells and superlattices, currently used by the conventional semiconductor industry, we show how copolymers consisting of sections of carbon and BN can be designed to tune the electronic properties of these new materials.


PACS

81.05.Zx New materials: theory, design, and fabrication

71.20.Rv Polymers and organic compounds

81.05.Lg Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials

71.15.Nc Total energy and cohesive energy calculations

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 42 (28 October 2002)

Received 31 May 2002

Published 11 October 2002



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