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Dynamical quantum filtering in the scattering dynamics of H2 on Cu(001)

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Yoshio Miura1,2, Hideaki Kasai2 and Wilson Agerico Diño2,3

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LETTER TO THE EDITOR

We investigate and discuss the effects of dynamical quantum filtering on the scattering dynamics of H2 on Cu(001); we perform coupled-channel calculations, including all six degrees of freedom of H2, on an ab initio potential energy surface. Our results show that cartwheel-like rotating H2 molecules (with their angular momentum vectors j predominantly oriented parallel to the surface) exhibit strong specular scattering on Cu(001), while helicopter-like rotating H2 molecules (with their angular momentum vectors j predominantly oriented perpendicular to the surface) exhibit off-specular scattering on Cu(001). These results indicate that we can obtain H2 molecules with aligned angular momentum vectors j, by scattering them from solid surfaces.


PACS

68.49.Df Molecule scattering from surfaces (energy transfer, resonances, trapping)

82.20.Kh Potential energy surfaces for chemical reactions

Subjects

Surfaces, interfaces and thin films

Chemical physics and physical chemistry

Dates

Issue 25 (1 July 2002)

Received 15 May 2002

Published 14 June 2002



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