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Magnetic properties of iridium pyrochlores R2Ir2O7 (R = Y, Sm, Eu and Lu)

Nobuyuki Taira, Makoto Wakeshima and Yukio Hinatsu

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Magnetic susceptibility, magnetic hysteresis, Mössbauer effect, and specific heat measurements were performed for R2Ir2O7 (R = Y, Sm, Eu and Lu), which show magnetic transitions at 150, 115, 120 and 120 K, respectively. Below the transition temperatures there is a large difference in the temperature dependence of the magnetization measured under zero-field-cooled conditions (ZFC) and under field-cooled conditions (FC), but no magnetic hysteresis loop has been observed. The magnetic properties of the Ir pyrochlores are similar to those of isostructural Ru pyrochlores. No sharp anomaly is observed in specific heat data for any of these compounds down to 1.8 K. These results suggest that R2Ir2O7 shows spin-glass-like behaviour below the transition temperatures.


PACS

75.30.Cr Saturation moments and magnetic susceptibilities

76.80.+y Mössbauer effect; other γ-ray spectroscopy

75.40.Cx Static properties (order parameter, static susceptibility, heat capacities, critical exponents, etc.)

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

Subjects

Condensed matter: electrical, magnetic and optical

Dates

Issue 23 (11 June 2001)

Received 19 February 2001, in final form 9 March 2001



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