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Kondo insulating behaviour in the filled skutterudite compound CeOs4Sb12

E D Bauer, A Slebarski1, E J Freeman, C Sirvent2 and M B Maple

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The filled skutterudite CeOs4Sb12 and its nonmagnetic analogue LaOs4Sb12 have been synthesized in single-crystal form using the molten-metal-flux growth technique with Sb flux. Electrical resistivity measurements on CeOs4Sb12 indicate that it is a Kondo insulator with an energy gap of ΔE/kB~10 K. Lattice parameter and magnetic susceptibility measurements suggest that the Ce ions are trivalent in CeOs4Sb12. Specific heat and magnetization measurements reveal an enhanced value of the electronic specific heat coefficient γ~92 mJ mol-1 K-2 and Pauli susceptibility, reminiscent of a moderately heavy-fermion material.


PACS

81.10.Dn Growth from solutions

72.20.-i Conductivity phenomena in semiconductors and insulators

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

72.80.Sk Insulators

75.30.Cr Saturation moments and magnetic susceptibilities

75.40.Cx Static properties (order parameter, static susceptibility, heat capacities, critical exponents, etc.)

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Condensed matter: structural, mechanical & thermal

Dates

Issue 20 (21 May 2001)

Received 30 March 2001



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