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Structural phase transition accompanied by metal-insulator transition in PrRu4P12

C H Lee1, H Matsuhata1, A Yamamoto1, T Ohta1, H Takazawa1, K Ueno1, C Sekine2, I Shirotani2 and T Hirayama3

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LETTER TO THE EDITOR

A structural phase transition has been found using electron diffraction technique in PrRu4P12 accompanied by a metal-insulator (M-I) transition (TMI = 60 K). Weak superlattice spots appeared at (H,K,L) (H + K + L = odd) position at a temperature of T = 12 K and 40 K. Above T = 70 K, the spots completely vanished. The space group of the low-temperature phase is probably Pmbar 3. This is the first observation of a symmetry other than Imbar 3 in skutterudite compounds.


PACS

71.30.+h Metal-insulator transitions and other electronic transitions

61.50.Ah Theory of crystal structure, crystal symmetry; calculations and modeling

68.65.Cd Superlattices

64.70.K- Solid–solid transitions

61.05.J- Electron diffraction and scattering

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Dates

Issue 2 (15 January 2001)

Received 4 October 2000



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