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Crystal-field interaction at the thulium site in

G A Stewart-+, S J Harker-+ and D M Pooke++

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Mössbauer spectroscopy is used to monitor the quadrupole interaction for the superconductor as a function of temperature. Qualitative comparison with other results supports earlier claims that the rank-2 crystal-field contribution lies between that for and that for . However, there is quantitative disagreement with crystal-field parameters determined elsewhere for .


PACS

74.72.Jt Other cuprates, including Tl and Hg-based cuprates

71.70.Jp Nuclear states and interactions

76.80.+y Mössbauer effect; other γ-ray spectroscopy

71.70.Ch Crystal and ligand fields

Subjects

Superconductivity

Condensed matter: electrical, magnetic and optical

Dates

Issue 37 (21 September 1998)

Received 8 April 1998, in final form 3 July 1998



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